Research Catalog

Title

The Anomeric effect and associated stereoelectronic effects / Gregory R.J. Thatcher, editor.

Publication

Washington, DC : American Chemical Society, 1993.

Items in the Library & Off-site

Holdings

Details

Additional Authors

• Thatcher, Gregory Robert James, 1959-
• American Chemical Society. Division of Carbohydrate Chemistry.
• American Chemical Society. Meeting (204th : 1992 : Washington, D.C.)

Description

xi, 305 pages : illustrations; 24 cm.

Series Statement

ACS symposium series ; 539

Uniform Title

ACS symposium series ; 539.

Subjects

• Stereochemistry
• Isomerism

Note

• "Developed from a symposium sponsored by the Division of Carbohydrate Chemistry at the 204th National Meeting of the American Chemical Society, Washington, DC, August 23-28, 1992."

Bibliography (note)

• Includes bibliographical references and indexes.

Contents

• 1. Anomeric Effect: How It Came To Be Postulated / John T. Edward -- 2. Anomeric and Associated Stereoelectronic Effects: Scope and Controversy / Gregory R. J. Thatcher -- 3. Intramolecular Strategies and Stereoelectronic Effects: Glycosides and Orthoesters Hydrolysis Revisited / P. Deslongchamps -- 4. Anomeric and Gauche Effects: Some Basic Stereoelectronics / Anthony J. Kirby and Nicholas H. Williams -- 5. Anomeric Effects: An Iconoclastic View / Charles L. Perrin -- 6. No Kinetic Anomeric Effect in Reactions of Acetal Derivatives / Michael L. Sinnott -- 7. Involvement of n[sigma]* Interactions in Glycoside Cleavage / C. Webster Andrews, Bert Fraser-Reid and J. Phillip Bowen -- 8. X-C-Z Anomeric Effect and Y-C-C-Z Gauche Effect (X,Y = O,S; Z = O,N): Evaluation of the Steric, Electrostatic, and Orbital Interaction Components / B. Mario Pinto and Ronald Y. N. Leung -- 9. Origin and Quantitative Modeling of Anomeric Effect / Peter A. Petillo and Laura E. Lerner.
• 10. Application of Quantum Theory of Atoms in Molecules to Study of Anomeric Effect in Dimethoxymethane / N. H. Werstiuk, K. E. Laidig and J. Ma -- 11. Anomeric and Reverse Anomeric Effect in Acetals and Related Functions / F. Grein -- 12. Glycosylmanganese Complexes and Anomeric Anomalies: The Next Generation? / Philip DeShong, Thomas A. Lessen, Thuy X. Le, Gary Anderson, D. Rick Sidler, Greg A. Slough, Wolfgang von Philipsborn, Markus Vohler and Oliver Zerbe -- 13. Do Stereoelectronic Effects Control the Structure and Reactivity of Trigonal-Bipyramidal Phosphoesters? / Philip Tole and Carmay Lim -- 14. Stereoelectronic Effects in Pentaoxysulfuranes: Putative Intermediates in Sulfuryl-Group Transfer / Dale R. Cameron and Gregory R. J. Thatcher -- 15. O-C-N Anomeric Effect in Nucleosides: A Major Factor Underlying the Experimentally Observed Eastern Barrier to Pseudorotation / Ravi K. Jalluri, Young H. Yuh and E. Will Taylor.

ISBN

0841227292 (acid-free paper)

LCCN

93034423

OCLC

ocm28966710

Owning Institutions

Columbia University Libraries