Research Catalog

Title

Carbenes, nitrenes and arynes [by] T.L. Gilchrist [and] C.W. Rees.

Author

Gilchrist, T. L. (Thomas Lonsdale)

Publication

New York, Appleton-Century-Crofts [©1969]

Items in the Library & Off-site

Details

Additional Authors

Rees, Charles W. (Charles Wayne)

Description

vi, 131 pages illustrations; 23 cm.

Series Statement

Studies in modern chemistry

Uniform Title

Studies in modern chemistry

Subject

• Carbenes (Methylene compounds)
• Nitrenes
• Benzene
• Chemistry, Organic
• Chemistry, Organic
• Benzene
• benzene
• organic chemistry
• Nitrenes
• Carbènes
• Nitrènes
• Benzène
• Arynes

Bibliography (note)

• Bibliography: p. 128.

Contents

1 : Structure and relationship of the intermediates -- 1-1 : Definitions and nomenclature -- 1-2 : Substituents and structure -- 1-3 : General methods of formation -- 1-4 : Evidence of the intermediates in reactions -- 2 : Generation of carbenes -- 2-1 : Introduction -- 2-2 : Carbenes from diazoalkanes, ketens, and ylids -- 2-3 : Carbenes by other fragmentations -- 2-4 : Carbenes from carbanions -- 2-5 : Carbenoids -- 2-6 : Other carbene-forming reactions -- 3 : Generation of nitrenes -- 3-1 : Introduction -- 3-2 : From azides -- 3-3 : Other thermolytic and photolytic routes -- 3-4 : From nitrogen anions -- 3-5 : Oxidative routes -- 3-6 : Reductive routes -- 3-7 : Other routes -- 4 : Generation of aryenes -- 4-1 : Introduction -- 4-2 : From aryl anions -- 4-3 : From aryl cations -- 4-4 : From zwitterions -- 4-5 : From aryl radicals -- 4-6 : By fragmentation of cyclic systems -- 5 : Cycloaddition reactions of carbenes -- 5-1 : Introduction -- 5-2 : Mechanism of the cycloaddition -- 5-3 : Cycloadditions to olefins -- 5-4 : Cycloadditions to allenes and acetylenes -- 5-5 : Cycloadditions to aromatic systems -- 5-6 : Cycloadditions to other unsaturated systems -- 5-7 : Carbenoid cycloadditions -- 6 : Reactions of carbenes : insertions and other reactions -- 6-1 : Insertion reactions -- 6-2 : Skeletal rearrangements -- 6-3 : Reactions with nucleophiles -- 6-4 : Dimerization -- 6-5 : Carbenes in transition-metal complexes -- 7 : Reactions of nitrenes -- 7-1 : Introduction -- 7-2 : Cycloaddition reactions -- 7-3 : Insertion reactions -- 7-4 : 1,2-shifts -- 7-5 : Dimerization -- 7-6 : Other reactions of aminonitrenes -- 7-7 : Reactions of nitrenes with nucleophiles -- 7-8 : Transition-metal complexes -- 8: Reactions of aryenes -- 8-1 : Introduction -- 8-2 : Cycloadditions -- 8-3 : Reactions and nucleophiles -- 8-4 : Reactions with electrophiles and radicals -- 8-5 : Dimerization and trimerization -- 8-6 : Transition-metal complexes -- 9 : Synthetic applications -- 9-1 : Introduction -- 9-2 : Dihalogenocarbenes -- 9-3 : Diels-Alder reactions of benzyne -- 9-4 : Intramolecular cyclizations via aryene intermediates -- 9-5 : Cine-substitution via aryenes.

ISBN

• 0177617039
• 9780177617034

LCCN

75418217

OCLC

• ocm00717543
• 717543
• SCSB-293133

Owning Institutions

Princeton University Library