Research Catalog

Thio- and dithiocarboxylic acids and their derivatives

Title
Thio- and dithiocarboxylic acids and their derivatives / S. Scheithauer and R. Mayer.
Author
Scheithauer, S.
Publication
Stuttgart : Thieme, 1979.

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StatusFormatAccessCall NumberItem Location
TextUse in library QD181.S1 xT6 vol.4Off-site

Details

Additional Authors
Mayer, Roland
Description
373 pages; 23 cm.
Series Statement
Topics in sulfur chemistry ; v. 4, 0342-4545
Subject
  • Carboxylic acids
  • Thiocarbonyl compounds
  • Carboxylic Acids
  • Dithiocarbonsäuren
  • Schwefelverbindungen
  • Thiocarbonsäuren
  • Soufre
  • Acide carboxylique
Bibliography (note)
  • Includes bibliographical references and index.
Contents
SYNTHESIS OF DITHIOCARBOXYLIC ACIDS AND THEIR DERIVATIVES: Preparation of dithiocarboxylic acids, their salts and metal complexes -- Synthesis of thiocarboxylic halides and pseudohalides and of thiocarboxylic anhydrides -- Preparation of thiocarboxylic O-Esters, dithiocarboxylic esters,and thiolactones -- PHYSICOCHEMICAL AND SPECTRAL PROPERTIES OFTHIOCARBOXYLIC ACIDS AND THEIR DERIVATIVES: Spectral properties of thiocarboxylic acid and their derivatives in the UV-visible region -- IR-spectral behavior of thiocarboxylic acid derivatives -- NMR spectra of thiocarboxylic acid derivatives -- EPR spectra -- Mass spectra -- Dipole moments of thiocarboxylic acid derivatives -- Physical characterization and structure determination of salts and complexes of dithiocarboxylic acids -- Acidity of thioacids -- Tautomerism of thioacids and their derivatives; formation of chelates -- REACTIONS: Nucleophilic attack at the carbon atom of the thiocarbonyl group. dithiocarboxylic acids and their derivatives as thioacylating agents -- Electrophilic attack at the thiocarbonyl function and at the adjacent site -- Oxidation, reduction, and desulfurization reactions -- Addition reactions at the thiocarbonyl group of thiocarboxylic acid derivatives -- Rearrangements -- TECHNICAL APPLICATION OF THIOCARBOXYLIC DERIVATIVES: As vulcanization accelerators, inhibitors, antioxidants, plastic modifiers, and flotation agents -- Dithiocarboxylic acids and their esters as starting materials for the synthesis of dyes and photosensitizers -- Use of fluorothiocarbonyl compounds -- BIOLOGICAL ACTIVITY.
ISBN
  • 3135264017
  • 9783135264011
LCCN
80486909
OCLC
  • ocm06816008
  • 6816008
  • SCSB-79214
Owning Institutions
Princeton University Library