Research Catalog

Dimensional scaling in chemical physics

Title
Dimensional scaling in chemical physics / edited by Dudley R. Herschbach, John Avery, and Osvaldo Goscinski.
Publication
Dordrecht ; Boston : Kluwer Academic Publishers, 1993.

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Details

Additional Authors
  • Herschbach, Dudley R.
  • Avery, John, 1933-
  • Goscinski, Osvaldo.
Description
510 pages : illustrations; 25 cm
Subject
  • Quantum chemistry
  • Scaling laws (Statistical physics)
  • Chimie quantique
  • Lois d'échelle (Physique statistique)
  • Skalierung
  • Statistische Mechanik
  • Quantenchemie
  • Quantum theory
Note
  • "August 27, 1992."
  • Includes bibliographical references and index.
Bibliography (note)
  • Includes bibliographical references and index.
Contents
I. Basic Aspects -- 1. Introduction -- 2. Tutorial -- II. The Research Frontier -- 3. Large-D Limit for N-Electron Atoms -- 4. Low D Regime -- 4.1. The One-Dimension Limit -- 4.2. Flatland: The Periodic System for D = 2 -- 5. Hyperspherical Symmetry -- 5.1. D-Dimensional Hydrogenlike Orbitals -- 5.2. Ground-State Wigner Function for the D-dimensional Hydrogen Atom -- 5.3. 1/n Expansions for Quasistationary States -- 6. Hypercylindrical Symmetry -- 6.1. The Spheroidal H Atom -- 6.2. 1/n Expansion for a Hydrogen Atom in Strong External Fields -- 6.3. Simple Molecules and Variant Scalings -- 6.4. Symmetry-breaking and Tunneling in H[actual symbol not reproducible] -- 7. General Computational Strategies -- 7.1. Singularity Analysis and Summation of 1/D Expansions -- 7.2. Dimensional Scaling and Spectral Properties -- 7.3. The Dimensional Dependence of Rates of Convergence of Rayleigh-Ritz Variational Calculations on Atoms and Molecules -- 8. Two-Electron Excited States -- 8.1. Dimensional Expansions for Excited States -- 8.2. Analytic Continuation of Higher Angular Momentum States to D Dimensions and Interdimensional Degeneracies -- 9. Large-D Limit for Metalic Hydrogen -- 10. D-Interpolation of Virial Coefficients -- III. Related Methods -- 11. Nonseparable Dynamics -- 12. Pseudomolecular Electron Correlation in Atoms -- 12.1. The Three-Body Coulomb Problem in Molecular Coordinates -- 12.2. Valence Electrons in Atoms: Collective or Independent-Particle-Like?
ISBN
  • 0792320360
  • 9780792320364
  • 0792320727
  • 9780792320722
LCCN
92035070
OCLC
  • ocm26852101
  • 26852101
  • SCSB-1973058
Owning Institutions
Princeton University Library